Toxic Gas Purchase Questionnaire

Purpose and Instructions

Purpose: The purpose of this questionnaire is to provide EH&S with information on control measures in place for toxic gases prior to purchase and to ensure compliance with the Santa Clara County Toxic Gas Ordinance (TGO). Instructions: 1.    Complete this questionnaire prior to each purchase of a toxic gas. 2.    EH&S will review the questionnaire and contact you to approve the purchase or obtain more information. If you have any questions, please send an email to toxicgases@lists.stanford.edu or contact the Laboratory Safety program at 723-0448. Information on the TGO, including a toxic gas table, is available at https://ehs.stanford.edu/topic/hazardous-materials/toxic-gas


Purchaser Information

Stanford SUNet email only, no email alias

Stanford SUNet email only, no email alias

Select
Caret IconCaret symbol

Toxic Gas to be Purchased

Select
Caret IconCaret symbol

Provide each gas (abbreviation okay) and percentage in the mixture, including diluent

Lbs and/or cubic feet at normal temperature and pressure

Select or enter value
Caret IconCaret symbol
Select
Caret IconCaret symbol
Select
Caret IconCaret symbol

Standard Operating Procedure (SOP) for Toxic Gas Use

An SOP template for toxic gases is available at https://ehs.stanford.edu/wp-content/uploads/sops/SOP-template-toxic-gases.docx. If an SOP has not previously been submitted to EH&S, use this form (https://app.smartsheet.com/b/form/6af14bd85ac64e2b90ddd7f16ee91fdb ) to submit one. An SOP is required for work with Toxic Gases.

Select
Caret IconCaret symbol

The PI/Supervisor must approve the SOP in writing. If it has not been approved in writing, do not select "yes".

Select
Caret IconCaret symbol

Confirm users of the toxic gas(es) associated with this order will complete or have completed compressed gas safety training (EHS-2200 or 4875) and all other safety training listed in the SOP prior to working with the toxic gas.

Select
Caret IconCaret symbol

Inventory

Is this the first time this gas is being used for this procedure/experiment?

Select
Caret IconCaret symbol

Will the cylinder being ordered increase your current inventory of this gas? EH&S must determine if the quantity of gas being purchased will exceed control area limits.

Select
Caret IconCaret symbol

This is a good practice so as to minimize the quantity of hazardous materials in the lab

Select
Caret IconCaret symbol

Is the gas being purchased in the lowest concentration possible for the intended use?

Select
Caret IconCaret symbol

Control Measures

Will the gas be purchased with a restrictive flow orifice (RFO) installed in cylinder? Per the TGO, all cylinders of Class I toxic gases, except lecture bottles and materials having a vapor pressure that does not exceed 29 psia, must be equipped with an RFO, if available. This includes cylinders of exempt quantities. If an RFO is not available, the cylinder must be used with a flow-limiting device. RFOs are recommended by EH&S for all toxic gas use. More information on RFOs is available at: • http://www.mathesongas.com/pdfs/products/Restrictive-Flow-Orifices.pdf • http://www.airproducts.com/company/Sustainability/environment-health-and-safety/~/media/Files/PDF/company/safetygram-46.pdf

Select
Caret IconCaret symbol

Are the piping, fittings, and equipment compatible with the gas and able to withstand the temperatures and pressures of the procedure?

Select
Caret IconCaret symbol

Are there anchored racks or other measures in place for securing cylinders?

Select
Caret IconCaret symbol

Are the gas cylinder, piping, and equipment using the gas all located within a laboratory fume hood? This is requested for informational purposes. This control measure is appropriate for some uses.

Select
Caret IconCaret symbol

Hazardous Waste Minimization

Is the gas being purchased in a returnable cylinder? Check with the vendor.

Select
Caret IconCaret symbol